Organic Chemistry-I

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Overview



Number of Credits =4

This course is a 4 credit course (15 weeks, 40 module) for M. Sc. Chemistry Students. Here, Students will be trained to improve their factual, conceptual, procedural and metacognitive knowledge. The scientific explanation given in the video contents makes use of the following components: Presentations, chemical structures, figures, tables, images, 3D-animations, white board demonstration, use of molecular models, paper 3D-models, mirrors etc. We gave emphasis to instructional design by leveraging theories based on Malcom Knowels Andragogy, modified Bloom’s taxonomy, the Feynman Technique, ADDIE model, Dick and Carey model, neuro slide design principles etc.

Facebook page:https://www.facebook.com/MoocOrganicChemistry1/
WhatsApp group:https://chat.whatsapp.com/invite/HTr5PdAvLoK3DcyhNSVBkO

Syllabus

COURSE LAYOUT

Week 1

Introduction to stereochemistry Conformational analysis of open chain systems Conformational analysis of cyclic systems


Week 2

Symmetry elements, Point group analysis Stereochemical conventions


Week 3

Stereogenicity, Topicity ORD and CD, Axial halo ketone rule, Octant Rule


Week 4

Stereochemical reactions Reactions involving stereo centres Crams Rule, Felkin-Anh model, Prelog rules


Week 5

Aromaticity, Aromatic stabilization energy, Hückel MO, Musulin-Frost diagram Polycyclic aromatic hydrocarbon (PAH), Polyacenes, Annulene


Week 6

Aromatic Electrophilic substitutions Aromatic Nucleophilic substitutions Ipso-cine-tele substitution


Week 7

Reaction dynamics, Hammond postulate Linear free energy relationship, Hammett equation


Week 8

Yukawa Tsuno equation, Swain-Lupton equation, Grunwald–Winstein equation, Taft equation Curtin-Hammett principle, Winstein-Holness equation

Carbocation, Part 1: Generation, Structure and Geometry


Week 9

Carbocation, Part 2: Stabilisation of carbocation, Reactions

Carbocation, Rearrangement 1: No Change in carbon skeleton, Change in carbon skeleton

Carbocation, Rearrangement 2: involvement of other electron deficient terminus, Anchimeric assistance


Week 10

Carbanions: pKa and its significance

Carbanions: Hard and Soft Acid and Base principle

Carbanions: Structure, Formation, Stability, Reactivity


Week 11

Carbanion reactions: Acyl Anions, Benzoin condensation, Umpolung-inversion of reactivity

Free radical 1: Formation, Structure, Stability

Free radical 2: Stability, Reactivity


Week 12

Free radical 3: Reactions

Carbene, Nitrene: Generation, Structure, Reactivity


Week 13

Carbonyl addition reaction


Week 14

Carbonyl addition reaction


Week 15

Name reactions

Exam